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N-Ferrocenylmethyl-2-(3-methylstyryl)-N’-methylbenzimidazolium hexafluorophosphate

Gallagher, John F. and Hanlon, Keith and Howarth, Joshua (2007) N-Ferrocenylmethyl-2-(3-methylstyryl)-N’-methylbenzimidazolium hexafluorophosphate. Acta Crystallographica Section E, 63 (11). ISSN 1600-5368

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Abstract

In the title compound, [Fe(C5H5)(C23H22N2)]PF6, the F atoms of the [PF6]- anion are disordered over four different orientations with equal occupancies. In the cation, the five-membered imidazolium ring forms dihedral angles of 71.48 (10) and 19.83 (10)° with the substituted C5H4 ring and the benzene ring of the styryl group, respectively. In the crystal structure, there is a significant C-H...[pi]([eta]5-C5H4) interaction.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S1600536807047769
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:102
Deposited On:19 Nov 2007 by DORAS Administrator. Last Modified 30 Jan 2009 15:15

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