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2-(3-Chlorophenyl)-1-ferrocenylmethyl-1H-1,3-benzimidazole: an electroactive agent for anion sensor and malarial parasite studies

Gallagher, John F. and Hanlon, Keith and Howarth, Joshua and Thomas, Jean-Luc (2001) 2-(3-Chlorophenyl)-1-ferrocenylmethyl-1H-1,3-benzimidazole: an electroactive agent for anion sensor and malarial parasite studies. Acta Crystallographica Section E, 57 (4). pp. 134-136. ISSN 1600-5368

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Abstract

The title compound, [Fe(C₅H₅)(C₁₉H₁₄ClN₂)], a model electroactive agent for anion sensor and malarial parasite studies, has Fe-C bond lengths in the range 2.020 (3)-2.0543 (18) Å. The Fe...Cg distances (Cg indicates a ring centroid) are essentially similar, with values of 1.6467 (10) and 1.6487 (11) Å for the substituted and unsubstituted cyclopentadienyl rings, respectively, with a linear Cg...Fe...Cg angle of 179.12 (7)°. The Fe-CCp-Csp³ angle is 128.43 (13)° and the Fe1-CCp-Csp³-NBz torsion angle 110.27 (17)° (Cp is cyclopentadienyl and Bz is benzimidazole). Weak C-H...Cl contacts form the only intermolecular interactions of significance.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Medical Sciences > Diseases
Physical Sciences > Chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S1600536801003804
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:156
Deposited On:22 Jan 2008 by DORAS Administrator. Last Modified 02 Feb 2009 11:51

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