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Marked differences in the 3p photoabsorption between the Cr and Mn⁺ isoelectronic pair: reasons for the unique structure observed in Cr

Cooper, J. and Clark, C. and Cromer, C. and Lucatorto, T. and Sonntag, B. and Kennedy, Eugene T. and Costello, John T. (1989) Marked differences in the 3p photoabsorption between the Cr and Mn⁺ isoelectronic pair: reasons for the unique structure observed in Cr. Physical Review A, 39 (11). pp. 6074-6077. ISSN 0556-2791

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Abstract

Chromium is the only member of the transition-group elements with a well developed Rydberg structure appearing in its 3p-absorption spectrum. New high-resolution measurements of Mn, Mn+, and Cr have revealed weak Rydberg structure in Mn+ and an analysis of the data shows that the anomalous Cr 3p absorption spectra is due to a unique relationship between its energy levels, and not to the previously supposed fact that Cr has an unpaired 4s electron.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Physics
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Physical Sciences
Publisher:The American Physical Society
Official URL:http://dx.doi.org/10.1103/PhysRevA.39.6074
Copyright Information:© 1989 The American Physical Society
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:15622
Deposited On:05 Aug 2010 17:10 by DORAS Administrator. Last Modified 05 Aug 2010 17:10

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