4p-inner-shell and double-excitation spectrum of Sr II
Banahan, Caroline and Costello, John T. and Kilbane, Deirdre and van Kampen, Paul (2009) 4p-inner-shell and double-excitation spectrum of Sr II. Physical Review A, 79 (2). 022509-1-022509-10. ISSN 1050-2947
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We report photoabsorption measurements from the 4p inner shell of singly ionized strontium in the spectral region between 26.0 and 37.4 eV. More than 60 levels of Sr II are reported which are interpreted as singly excited inner-shell transitions 4p65s 2S1∕2→4p45s(1P,3P)ns, md and doubly excited transitions 4p65s 2S1∕2→4p54d(1P,3P,3D)nl. Multiconfiguration Hartree-Fock calculations are performed in jj coupling and the levels are arranged into Rydberg series converging on seven limits, allowing the identification of two levels in Sr III.
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