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Stimuli-responsive materials for self-reporting micro-fluidic devices

Florea, Larisa and Dunne, Aishling and Francis, Wayne and Bruen, Danielle and Tudor, Alexandru and Diamond, Dermot (2016) Stimuli-responsive materials for self-reporting micro-fluidic devices. In: IC-ANMBES 2016 , 29 Jun - 1 Jul 2016 , Brasov, Romania.

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The integration of stimuli-responsive materials into microfluidic systems can provide a means for external control over fluid flow along with inherent sensing capabilities, which can reduce the overall complexity of microfluidic devices. Herein we present several approaches for introducing fluid movement and sensing using stimuli-responsive materials. The first approach comprises the use of adaptive nanostructured coatings for direct sensing of flow in continuous flow mode. For this, the inner walls of micro-capillaries and micro-channels were coated with polymeric materials that can be used to detect a variety of target species. Two types of adaptive coatings will be discussed. The first one is based on the conductive polymer polyaniline (PAni) [1,2] while the second consists of polymeric brushes based on spiropyran [3,4]. Using the “grafting” approach homogeneous coatings were obtained on the micro-channel/micro-capillary surface that retained their inherent nano-morphology. The optical proprieties of these coatings change in response to a variety of target analytical species (divalent metal ions, solvents of different polarities, ammonia, H+) passing through the microfluidic device in continuous flow mode. The grafting approach can provide nanostructured to microstructured coatings that combine small diffusion paths with relatively thick optical path lengths, thereby providing sensitive and fast optical responses to the target analytes. The second approach comprises the use of porous photo-actuated hydrogels as photo-controlled micro-valves in microfluidic systems for repeatable ON/OFF flow modulation in flowing streams over a wide range of pH values (acidic to ca. pH 7.0). Incorporation of such stimuli-controlled structures in microfluidic devices offers unprecedented versatility and external flow control. We envision using these systems to create a new generation of sustainable, low-cost, photonically-controlled and self-reporting fluidic systems. 1. Florea, L.; Diamond, D.; Benito-Lopez, F.,. Anal. Chim. Acta 2013, 759, 1-7. 2. Florea, L. et al., Lab Chip 2013, 13, 1079-1085. 3. Florea, L. et al., Sens. Actuators, B 2012, 175, 92-99. 4. Florea, L. et al., Langmuir 2013, 29, 2790-2797.

Item Type:Conference or Workshop Item (Lecture)
Event Type:Conference
Uncontrolled Keywords:Stimuli-responsive; Spiropyran; Photochromism; Microfluidics; Polyaniline; Adaptive coatings
Subjects:Physical Sciences > Analytical chemistry
Physical Sciences > Photochemistry
Physical Sciences > Organic chemistry
Physical Sciences > Chemistry
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Research Initiatives and Centres > INSIGHT Centre for Data Analytics
Research Initiatives and Centres > National Centre for Sensor Research (NCSR)
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
Funders:Science foundation Ireland under the Insight initiative, grant SFI/12/RC/2289.
ID Code:21278
Deposited On:26 Jul 2016 11:34 by Larisa Florea. Last Modified 26 Apr 2017 11:33

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