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2-Ferrocenyl-N-(2-ferrocenylbenzoyl)-N-(4-methyl-2-pyridyl)benzamide

Gallagher, John F. and Alley, Steven and Lough, Alan J. (2009) 2-Ferrocenyl-N-(2-ferrocenylbenzoyl)-N-(4-methyl-2-pyridyl)benzamide. Acta Crystallographica Section E, 65 (3). ISSN 1600-5368

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Abstract

The title compound, [Fe2(C5H5)2(C30H22N2O2)], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methylpyridine, forms a twisted molecular structure in the solid state due to steric effects from the two benzene rings ortho-substituted with ferrocenyl and carbonyl-derived groups. A short intramolecular C-H...[pi] interaction is observed involving a substituted [eta]5-C5H4 ring and an ortho H atom of the benzene ring on the opposite side of the molecule. In the crystal structure, there are no classical hydrogen bonds: interactions comprise a short C6-H...[pi](C6) interaction involving substituted benzene rings and two C-H...O=C interactions per molecule.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S1600536809006278
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:2442
Deposited On:03 Mar 2009 13:58 by DORAS Administrator. Last Modified 03 Mar 2009 13:58

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