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Chloro(trimesitylphosphine)gold(I)

Alyea, Elmer C. and Ferguson, George and Gallagher, John F. and Malto, John (1993) Chloro(trimesitylphosphine)gold(I). Acta Crystallographica Section C, 49 (8). pp. 1473-1476. ISSN 0108-2701

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Abstract

Chloro(trimesitylphosphine)gold(I), [AuCl(C9H11)P3], has approximate threefold symmetry in the solid state [dihedral angles between the mesityl ring planes and the relevant Au--PnC planes are 47.0(1), 48.0(1) and 48.5 (1)°]. The Au atom has a linear coordination geometry with AumC1 and Au--P bond lengths of 2.2716 (19) and 2.2634 (15) A, respectively, and a PmAu--C1 bond angle of 178.01 (8) °. The Ca~--Ca~ bond lengths are in the range 1.360 (10) to 1.424 (8) ,4,, while the range of Car--Csp3 distances lies between 1.499(10) and 1.529 (9) A.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270192012757
Copyright Information:© 1993 International Union of Crystallography
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:2461
Deposited On:11 Mar 2009 18:14 by DORAS Administrator. Last Modified 11 Mar 2009 18:14

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