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cis-Tetracarbonylbis[tris(p-fluorophenyl)phosphine]molybdenum(0)

Alyea, Elmer C. and Ferguson, George and Gallagher, John F. and Song, Shuquan (1994) cis-Tetracarbonylbis[tris(p-fluorophenyl)phosphine]molybdenum(0). Acta Crystallographica Section C, 50 (7). pp. 1084-1087. ISSN 0108-2701

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Abstract

The molecule c/s-tetracarbonylbis[tris(p-fluorophenyl)- phosphine] molybdenum(0), [Mo(C18HI2F3P)2(CO)4], has twofold crystallographic symmetry; the Mo geometry is irregular octahedral, with principal dimensions Mo- P 2.5644 (4), Mo--C (troans to P) 1.9869 (16), Mo--C (trans to C) 2.0310 (18) A, P--Mo--P 107.33 (1), trans- P--Mo--C 166.76 (5)and trans-C--Mo--C 174.31 (8)°. The P geometry is irregular tetrahedral, with enlarged Mo--P--C [average 115.94 (5)°] and reduced C--P--C [average 102.22 (7)°] angles. 95Mo NMR chemical shift data are in accord with the observed structure.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270193014052
Copyright Information:© 1994 International Union of Crystallography
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:2473
Deposited On:11 Mar 2009 17:54 by DORAS Administrator. Last Modified 11 Mar 2009 17:54

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