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Ethyl and isopropyl 4-ferrocenylbenzoate.

Anderson, Frankie P. and Gallagher, John F. and Kenny, Peter T.M. and Ryan, Clodagh and Savage, David (2002) Ethyl and isopropyl 4-ferrocenylbenzoate. Acta Crystallographica Section C, 59 (1). pp. 13-15. ISSN 0108-2701

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Abstract

The title compounds, [Fe(C5H5)(C14H13O2)] and [Fe(C5H5)- (C15H15O2)], respectively, contain the ferrocenyl 5(C5H4) and phenylene ±C6H4± rings in a nearly coplanar arrangement, with interplanar angles of 6.88 (12) and 10.5 (2), respectively. Molecules of the ethyl ester form dimers through 5(C5H5)CÐ H O C hydrogen bonds, with graph set R22 (20), and, together with Csp3ÐH (C5H5) interactions, generate a one-dimensional column (irregular ladder). Molecules of the isopropyl ester aggregate through 5(C5H5)CÐH (C6H4) interactions.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270102021819
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:26
Deposited On:08 Oct 2007 by DORAS Administrator. Last Modified 30 Jan 2009 09:33

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