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Intermolecular (pyrrole)N-H...π(pyrrole) interactions in bis(2-pyrrolyl)methylferrocene, an organometallic porphyrin precursor

Gallagher, John F. and Moriarty, Elena (1999) Intermolecular (pyrrole)N-H...π(pyrrole) interactions in bis(2-pyrrolyl)methylferrocene, an organometallic porphyrin precursor. Acta Crystallographica Section C, 55 (7). pp. 1079-1082. ISSN 0108-2701

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Abstract

The title compound, C₁₉H₁₈FeN₂ or [Fe(C₅H₅)(C₁₄H₁₃- N₂)], crystallizes in space group P2₁ln with two molecules in the asymmetric unit. The pyrrole groups take part in intermolecular (pyrrole)N--H...π(pyrrole) interactions through a hydrogen-bonded ring system involving four pyrrole groups, with N..-(pyrrole centroid) distances in the range 3.209(3)-3.427 (3)Å and N-- H...(pyrrole centroid) angles in the range 127-139°.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270199003625
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:296
Deposited On:11 Mar 2008 by DORAS Administrator. Last Modified 03 Feb 2009 13:01

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