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Photochemically induced isomerisation in ruthenium polypyridyl complexes

Fanni, Stefano and Weldon, Frances and Hammarström, Leif and Mukhtar, Emad and Browne, Wesley R. and Keyes, Tia E. and Vos, Johannes G. (2001) Photochemically induced isomerisation in ruthenium polypyridyl complexes. European Journal of Inorganic Chemistry, 2001 (2). pp. 529-534. ISSN 1434-1948

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Abstract

The synthesis and characterisation of a series of ruthenium polypyridyl complexes containing pyridyltriazole ligands in different coordination modes are described. The electrochemical and electronic properties of the compounds are reported and discussed with respect to the coordination mode of the pyridyltriazole ligand. Upon photolysis of the complex containing the 1-methyl-3-(pyridin-2-yl)-1,2,4-triazole ligand irreversible ligand isomerisation is observed.

Item Type:Article (Published)
Refereed:Yes
Uncontrolled Keywords:ruthenium; coordination modes; photochemistry;
Subjects:Physical Sciences > Chemistry
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Research Initiatives and Centres > National Centre for Sensor Research (NCSR)
Publisher:John Wiley & Sons
Official URL:http://dx.doi.org/10.1002/1099-0682(200102)2001:2<529::AID-EJIC529>3.0.CO;2-V
ID Code:34
Deposited On:27 Oct 2006 by DORAS Administrator. Last Modified 30 Jan 2009 11:11

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