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Structures of tribenzylmethanol and 1,2,3-triphenyl-2-propanol

Ferguson, George and Gallagher, John F. and Glidewell, Christopher and Liles, David C. and Zakaria, Choudhury M. (1993) Structures of tribenzylmethanol and 1,2,3-triphenyl-2-propanol. Acta Crystallographica Section C, 49 (4). pp. 820-824. ISSN 0108-2701

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Abstract

The tribenzylmethanol molecule, (PhCH2)3COH, has approximate threefold symmetry in the solid state. The hydroxyl H atom is disordered unequally over three orientations and is not involved in hydrogen bonding. The 1,2,3-triphenyl-2-propanol molecule, Ph(PhCH2)2COH, crystallizes with two molecules per asymmetric unit which differ slightly in conformation. In one of the molecules the hydroxyl H atom is disordered equally over two sites, whereas in the other molecule there is no disorder. As in the tribenzylmethanol molecule, there is no intermolecular O--H...O hydrogen bonding, presumably because of the steric bulk of the molecules and their packing which prevents the close approach of the O atoms of adjacent molecules.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270192011545
Copyright Information:© 1993 International Union of Crystallography
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:3625
Deposited On:20 Mar 2009 16:28 by DORAS Administrator. Last Modified 20 Mar 2009 16:28

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