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Inkjet printed LED based pH chemical sensor for gas sensing

O'Toole, Martina and Shepherd, Roderick and Wallace, Gordon and Diamond, Dermot (2009) Inkjet printed LED based pH chemical sensor for gas sensing. Analytica Chimica Acta, 652 (1-2). pp. 308-314. ISSN 0003-2670

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Predictable behaviour is a critical factor when developing a sensor for potential deployment within a wireless sensor network (WSN). The work presented here details the fabrication and performance of an optical chemical sensor for gaseous acetic acid analysis, which was constructed using inkjet printed deposition of a colorimetric chemical sensor. The chemical sensor comprised a pH indicator dye (bromophenol blue), phase transfer salt tetrahexylammonium bromide and polymer ethyl cellulose dissolved in 1-butanol. A paired emitter-detector diode (PEDD) optical detector was employed to monitor responses of the colorimetric chemical sensor as it exhibits good sensitivity, low power consumption, is low cost, accurate and has excellent signal to noise ratios. The chemical sensor formulation was printed directly onto the surface the emitter LED, and the resulting chemical sensors characterised with respect to their layer thickness, response time and recovery time. The fabrication reproducibility of inkjet printed chemical sensors in comparison to drop casted chemical sensors was investigated. Colorimetric chemical sensors produced by inkjet printing, exhibited an improved reproducibility for the detection of gaseous acetic acid with a relative standard deviation of 5.5 % in comparison to 68.0 % calculated for drop casted sensors (n = 10). The stability of the chemical sensor was also investigated through both intra and inter-day studies.

Item Type:Article (Published)
Subjects:Physical Sciences > Analytical chemistry
Physical Sciences > Detectors
Physical Sciences > Chemistry
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Research Initiatives and Centres > CLARITY: The Centre for Sensor Web Technologies
Research Initiatives and Centres > National Centre for Sensor Research (NCSR)
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Copyright Information:Copyright © 2009 Elsevier B.V.
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
Funders:Science Foundation Ireland, SFI 07/CE/1147
ID Code:4696
Deposited On:13 Jul 2009 16:03 by martina o'toole. Last Modified 02 Mar 2017 16:47

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