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Bis(μ-2,2,6,6,10,10-hexamethyl-4,8-dioxaundecanedioato-O¹,O¹¹:O¹',O¹¹')bis(pyridine-N)dirhodium(II)(Rh-Rh)

Gallagher, John F. and Ferguson, George and McAlees, Alan J. (1997) Bis(μ-2,2,6,6,10,10-hexamethyl-4,8-dioxaundecanedioato-O¹,O¹¹:O¹',O¹¹')bis(pyridine-N)dirhodium(II)(Rh-Rh). Acta Crystallographica Section C, 53 (5). pp. 576-579. ISSN 0108-2701

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Abstract

The title compound, [Rh₂(C₁₅H₂₆O₆)₂(C₅H₅N)₂], lies about an inversion centre which is at the midpoint of the Rh-Rh bond. The polyether dicarboxylate ligands bridge the Rh atoms and function as macrocyclic chelates to the Rh-Rh unit. A pyridine molecule is axially coordinated to each Rh atom completing the octahedral coordination. Main dimensions are Rh-Rh 2.4017 (2), Rh-O 2.0367 (9)-2.0405 (9), Rh-N 2.2540 (11) Å and Rh-Rh-N 178.59 (3)°.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S010827019700142X
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:564
Deposited On:15 Sep 2008 15:08 by DORAS Administrator. Last Modified 16 Feb 2009 16:28

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