Ferguson, George, Gallagher, John F. 
ORCID: 0000-0002-7112-7450, Fullwood, Russell and Parker, David
(1992)
(1R,2R)-1,2-Diphenyl-1,2-ethanediamine monohydrobromide.
Acta Crystallographica Section C, 48
(12).
pp. 2273-2275.
ISSN 0108-2701
Abstract
The cation in (1R,2R)- 1,2-diphenyl- 1,2-ethanediamine
monohydrobromide has approximate twofold symmetry
and is involved in a three-dimensional hydrogen-bond
network with the bromide anion [H...Br 2.51 (4)-2.82(3),
N...Br 3.279(2)-3.560(3) A]. Principal bond lengths
include Csp3--Csp 3 1.535(4), Csp3--NH~ 1.489(3),
Csp3--NH2 1.469(4), and Csp3--Car 1.517(3) and
1.528(3) A. The main torsion angles defining the conformation
are NH~--Csp3--Csp3--NH2 -44.3(2) and
Car--Csp3--Csp3--Car 64.3(2) °. The absolute stereochemistry
(known on chemical grounds) was confirmed
by the analysis.
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Subjects: | Physical Sciences > Organic chemistry Physical Sciences > Crystallography |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
| Publisher: | International Union of Crystallography |
| Official URL: | http://dx.doi.org/10.1107/S0108270192008953 |
| Copyright Information: | © 1992 International Union of Crystallography |
| Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
| ID Code: | 3614 |
| Deposited On: | 18 Mar 2009 18:02 by DORAS Administrator . Last Modified 10 Oct 2018 12:51 |
Documents
Full text available as:
Preview |
PDF
- Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
340kB |
Downloads
Downloads
Downloads per month over past year
Archive Staff Only: edit this record