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Intermolecular interactions in N-(ferrocenylmethyl)anthracene-9-carboxamide

Gallagher, John F. and Kelly, Paula N. and Kenny, Peter T.M. and Lough, Alan J. (2003) Intermolecular interactions in N-(ferrocenylmethyl)anthracene-9-carboxamide. Acta Crystallographica Section C, 59 (12). pp. 552-554. ISSN 0108-2701

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Abstract

The title compound, [Fe(C₅H₅)(C₂₁H₁₆NO)], was synthesized from the coupling reaction of anthracene-9-carboxylic acid and ferrocenylmethylamine. The ferrocenyl (Fc) group and the anthracene ring system both lie approximately orthogonal to the amide moiety. An amide-amide interaction (along the a axis) is the principal interaction [N...O = 2.910 (2) Å]. A C-H...π(arene) interaction [C...centroid = 3.573 (2) Å] and a C-H...O interaction [C...O = 3.275 (3) Å] complete the hydrogen bonding; two short (Fc)C...C(anthracene) contacts are also present.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Research Initiatives and Centres > National Institute for Cellular Biotechnology (NICB)
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S010827010302585X
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:143
Deposited On:18 Jan 2008 by DORAS Administrator. Last Modified 03 Feb 2009 12:50

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