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2-Ferrocenyl-N-(6-methyl-2-pyridyl)benzamide

Gallagher, John F. orcid logoORCID: 0000-0003-4130-4556, Alley, Steven and Lough, Alan J. (2010) 2-Ferrocenyl-N-(6-methyl-2-pyridyl)benzamide. Acta Crystallographica Section E, 66 (4). p. 396. ISSN 1600-5368

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Abstract
The title compound, [Fe(C5H5)(C18H15N2O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methylpyridine, crystallizes with two dissimilar molecules in the asymmetric unit. In one molecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, molecules aggregate into dimers via cyclic, asymmetric N-H...N interactions with graph set R22(8), and are further augmented via intramolecular C-H...O=C and interdimer C-H...[pi](arene) interactions. Dimers are linked into chains along the [102] direction via weak C-H...O hydrogen bonds.
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Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S1600536810008342
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:15329
Deposited On:22 Mar 2010 13:37 by DORAS Administrator . Last Modified 10 Oct 2018 11:44
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