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Delinquent sensors and schizophrenic materials: using molecular switches to make materials with multiple personalities

Byrne, Robert and Scarmagnani, Silvia and Benito-Lopez, Fernando and Radu, Aleksandar and Diamond, Dermot (2009) Delinquent sensors and schizophrenic materials: using molecular switches to make materials with multiple personalities. Irish Chemical News, 21 (38). pp. 26-28. ISSN 0790-4975

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In this paper, we consider the use of ‘adaptive’ materials (i.e. materials that can be switched reversibly between two or more different forms with radically different characteristics). This may open the way to the development of materials that can exist in a passive form (non-binding) until a measurement is required, at which point the material is switched to an ‘active’ form. Binding then occurs and a signal is generated, and the material subsequently switched back to the ‘passive’ form. We have demonstrated that binding of metal ions and amino acids at spiropyran modified surfaces can be controlled photonically using LEDs. It is possible that this may provide a route to more sophisticated materials whose host-guest binding behaviour and signal generation can be activated or deactivated on demand. This effect has important potential applications in sensors, purification resins, separation science and drug delivery. In this paper we report progress on the modification of several materials with spiropyran and their incorporation within microfluidic devices.

Item Type:Article (Published)
Subjects:Engineering > Materials
Physical Sciences > Detectors
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Research Initiatives and Centres > CLARITY: The Centre for Sensor Web Technologies
Research Initiatives and Centres > National Centre for Sensor Research (NCSR)
Publisher:Institute of Chemistry of Ireland
Official URL:
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
Funders:Science Foundation Ireland, Irish Research Council for Science Engineering and Technology, Enterprise Ireland
ID Code:2446
Deposited On:06 Mar 2009 16:55 by Dermot Diamond. Last Modified 16 Feb 2017 13:30

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