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(1,3-Butadiynyl-C¹)(η⁵-cyclopentadienyl)(triphenylphosphine-P)nickel(II)

Gallagher, John F. and Butler, Peter and Manning, Anthony R. (1998) (1,3-Butadiynyl-C¹)(η⁵-cyclopentadienyl)(triphenylphosphine-P)nickel(II). Acta Crystallographica Section C, 54 (3). pp. 342-345. ISSN 0108-2701

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Abstract

The title compound, [Ni(Cp)(PPh₃)(C≡C-C≡C-H)] or [Ni(C₄H)(C₅H₅)(C₁₈H₁₅P)], has metal-ligand dimensions of Ni--P 2.1410(4), Ni--C 1.8383 (15)Å and P--Ni--C 93.47 (5)°, and principal oalkyne dimensions of C≡C 1.212(2) and 1.187(3)Å, and C≡C-C 177.94(19) and 179.5(2)°. Intra- and intermolecular C--H...C≡C interactions are present with the shortest C...C distance being 3.198 Å.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270197016478
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:290
Deposited On:11 Mar 2008 by DORAS Administrator. Last Modified 03 Feb 2009 12:41

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