Gallagher, John F. 
ORCID: 0000-0003-4130-4556, Hudson, Richard D.A. and Manning, Anthony R.
(2001)
Intermolecular O-H...O and C-H...π(C5H5), and intramolecular C-H...O interactions in 2-(ferrocenyl)thiophene-3-carboxylic acid.
Acta Crystallographica Section C, 57
(1).
pp. 28-30.
ISSN 0108-2701
Abstract
The title compound, [Fe(C₅H₅)(C₁₀H₇O₂S)], an important precursor en route to organometallic donor-π-acceptor systems, forms dimers in the solid state through cyclic intermolecular carboxylic acid O-H...O hydrogen bonds, graph set R²₂(8) [O...O 2.661 (2) Å and O-H...O 175°]. Intermolecular Ccp-H...πcp interactions between the unsubstituted cyclopentadienyl (Cp) rings and Cthiazole-H...πcp interactions link neighbouring molecules into a three-dimensional network [C...Cg 3.753 (7) Å and C-H...Cg 156°, and C...Cg 3.687 (3) Å and C-H...Cg 129°; Cg is the ring centroid]. Intramolecular C-H...O interactions are present, graph set S(7) [C...O 2.925 (3) Å and C-H...O 120°, and the closest C-H...Sthienyl contact has a C...S distance of 3.058 (2) Å].
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Subjects: | Physical Sciences > Organic chemistry Physical Sciences > Chemistry Physical Sciences > Crystallography |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
| Publisher: | International Union of Crystallography |
| Official URL: | http://dx.doi.org/10.1107/S0108270100014360 |
| Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
| ID Code: | 153 |
| Deposited On: | 21 Jan 2008 by DORAS Administrator . Last Modified 10 Oct 2018 12:24 |
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