Login (DCU Staff Only)
Login (DCU Staff Only)

DORAS | DCU Research Repository

Explore open access research and scholarly works from DCU

Advanced Search

2-Ferrocenyl-N-(6-methyl-2-pyridyl)benzamide

Gallagher, John F. orcid logoORCID: 0000-0003-4130-4556, Alley, Steven and Lough, Alan J. (2010) 2-Ferrocenyl-N-(6-methyl-2-pyridyl)benzamide. Acta Crystallographica Section E, 66 (4). p. 396. ISSN 1600-5368

Abstract
The title compound, [Fe(C5H5)(C18H15N2O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methylpyridine, crystallizes with two dissimilar molecules in the asymmetric unit. In one molecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, molecules aggregate into dimers via cyclic, asymmetric N-H...N interactions with graph set R22(8), and are further augmented via intramolecular C-H...O=C and interdimer C-H...[pi](arene) interactions. Dimers are linked into chains along the [102] direction via weak C-H...O hydrogen bonds.
Metadata
Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S1600536810008342
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:15329
Deposited On:22 Mar 2010 13:37 by DORAS Administrator . Last Modified 10 Oct 2018 11:44
Documents

Full text available as:

[thumbnail of acta_crys_c_66_4.pdf]
Preview
PDF - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
416kB
Metrics

Altmetric Badge

Dimensions Badge

Downloads

Downloads

Downloads per month over past year

Archive Staff Only: edit this record