Gallagher, John F. ORCID: 0000-0003-4130-4556, Alley, Steven and Lough, Alan J. (2010) 2-Ferrocenyl-N-(6-methyl-2-pyridyl)benzamide. Acta Crystallographica Section E, 66 (4). p. 396. ISSN 1600-5368
Abstract
The title compound, [Fe(C5H5)(C18H15N2O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methylpyridine, crystallizes with two dissimilar molecules in the asymmetric unit. In one molecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, molecules aggregate into dimers via cyclic, asymmetric N-H...N interactions with graph set R22(8), and are further augmented via intramolecular C-H...O=C and interdimer C-H...[pi](arene) interactions. Dimers are linked into chains along the [102] direction via weak C-H...O hydrogen bonds.
Metadata
Item Type: | Article (Published) |
---|---|
Refereed: | Yes |
Subjects: | Physical Sciences > Organic chemistry Physical Sciences > Crystallography |
DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
Publisher: | International Union of Crystallography |
Official URL: | http://dx.doi.org/10.1107/S1600536810008342 |
Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
ID Code: | 15329 |
Deposited On: | 22 Mar 2010 13:37 by DORAS Administrator . Last Modified 10 Oct 2018 11:44 |
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