Gallagher, John F., Hanlon, Keith, Howarth, Joshua and Thomas, Jean-Luc (2001) 2-(3-Chlorophenyl)-1-ferrocenylmethyl-1H-1,3-benzimidazole: an electroactive agent for anion sensor and malarial parasite studies. Acta Crystallographica Section E, 57 (4). pp. 134-136. ISSN 1600-5368
Abstract
The title compound, [Fe(C₅H₅)(C₁₉H₁₄ClN₂)], a model electroactive agent for anion sensor and malarial parasite studies, has Fe-C bond lengths in the range 2.020 (3)-2.0543 (18) Å. The Fe...Cg distances (Cg indicates a ring centroid) are essentially similar, with values of 1.6467 (10) and 1.6487 (11) Å for the substituted and unsubstituted cyclopentadienyl rings, respectively, with a linear Cg...Fe...Cg angle of 179.12 (7)°. The Fe-CCp-Csp³ angle is 128.43 (13)° and the Fe1-CCp-Csp³-NBz torsion angle 110.27 (17)° (Cp is cyclopentadienyl and Bz is benzimidazole). Weak C-H...Cl contacts form the only intermolecular interactions of significance.
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Subjects: | Physical Sciences > Organic chemistry Medical Sciences > Diseases Physical Sciences > Chemistry Physical Sciences > Crystallography |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
| Publisher: | International Union of Crystallography |
| Official URL: | http://dx.doi.org/10.1107/S1600536801003804 |
| Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
| ID Code: | 156 |
| Deposited On: | 22 Jan 2008 by DORAS Administrator . Last Modified 19 Jul 2018 14:40 |
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