Vijayaraghavan, Rajani K. ORCID: 0000-0003-1096-448X, Daniels, Stephen, McGlynn, Enda ORCID: 0000-0002-3412-9035, Gandhiraman, Ram Prasad, Groarke, Robert and McNally, Patrick J. ORCID: 0000-0003-2798-5121 (2012) Low temperature growth technique for nanocrystalline cuprous oxide thin films using microwave plasma oxidation of copper. Materials Letters, 71 . pp. 160-163. ISSN 0167-577X
Abstract
We report on the direct formation of phase pure nanocrystalline cuprous oxide (Cu2O) film with band gap ~ 2 eV by microwave plasma oxidation of pulsed dc magnetron sputtered Cu films and the highly controlled oxidation of Cu in to Cu2O and CuO phases by controlling the plasma exposure time. The structural, morphological and optoelectronic properties of the films were investigated. p-type Cu2O film with a grain size ~20-30 nm, resistivity of ~66 Ω cm and a hole concentration of ~2×1017 cm-3 is obtained for a plasma exposure time of 10 min without using any foreign dopants. The optical absorption coefficient (~105 cm-1) of the Cu2O film is also reported.
Metadata
Item Type: | Article (Published) |
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Refereed: | Yes |
Uncontrolled Keywords: | Solar energy materials; Oxidation |
Subjects: | Engineering > Materials Physical Sciences > Spectrum analysis Physical Sciences > Nanotechnology Physical Sciences > Chemistry Physical Sciences > Semiconductors |
DCU Faculties and Centres: | Research Institutes and Centres > National Centre for Plasma Science and Technology (NCPST) DCU Faculties and Schools > Faculty of Science and Health > School of Physical Sciences |
Publisher: | Elsevier |
Official URL: | http://dx.doi.org/10.1016/j.matlet.2011.12.044 |
Copyright Information: | © 2012 Elsevier |
Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
ID Code: | 19629 |
Deposited On: | 08 Nov 2013 11:32 by Enda Mcglynn . Last Modified 09 Jun 2020 16:11 |
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