Crean, Colm, Gallagher, John F. 
ORCID: 0000-0003-4130-4556 and Pratt, Albert C.
(2002)
2,2'-[2,3-Dihydro-2-(prop-2-enyl)-1H-isoindole-1,3-diylidene]bis(propanedinitrile)-tetrathiafulvalene (1/1), TCPI-TTF.
Acta Crystallographica Section C, 58
(1).
pp. 36-38.
ISSN 0108-2701
Abstract
The title complex, C17H9N5•C6H4S4, contains -deficient bis(dinitrile) and TTF molecules stacked alternately in columns along the a-axis direction; the interplanar angle between the TTF molecule and the isoindolinyl C4N[C(CN)2]2 moiety is 1.21 (4)°. The N-allyl moiety in the TCPI molecule is oriented at an angle of 87.10 (10)° with respect to the five-membered C4N ring, and the four C N bond lengths range from 1.134 (3) to 1.142 (3) Å, with C-C N angles in the range 174.3 (3)-176.9 (2)°. In the TTF system, the S-C bond lengths are 1.726 (3)-1.740 (3) and 1.751 (2)-1.763 (2) Å for the external S-C(H) and internal S-C(S) bonds, respectively.
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Subjects: | Physical Sciences > Chemistry Physical Sciences > Crystallography |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
| Publisher: | International Union of Crystallography |
| Official URL: | http://dx.doi.org/10.1107/S0108270101017632 |
| Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
| ID Code: | 22 |
| Deposited On: | 05 Oct 2007 by DORAS Administrator . Last Modified 10 Oct 2018 12:14 |
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