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Directing the mechanism of CO2 reduction by a Mn catalyst through surface immobilization

Walsh, James J. orcid logoORCID: 0000-0003-4862-8449, Forster, Mark, Smith, Charlotte L., Neri, Gaia, Potter, Richard J. and Cowan, Alexander J. (2018) Directing the mechanism of CO2 reduction by a Mn catalyst through surface immobilization. Physical Chemistry Chemical Physics, 20 . pp. 6811-6816. ISSN 1463-9076

Abstract
Immobilization of a Mn polypyridyl CO2 reduction electrocatalyst on nanocrystalline TiO2 electrodes yields an active heterogeneous system and also significantly triggers a change in voltammetric and catalytic behaviour, relative to in solution. A combination of spectroelectrochemical techniques are presented here to elucidate the mechanism of the immobilised catalyst in-situ.
Metadata
Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Chemistry
Physical Sciences > Electrochemistry
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Research Institutes and Centres > National Centre for Sensor Research (NCSR)
Publisher:Royal Society of Chemistry
Official URL:DOI: 10.1039/C7CP08537K
Copyright Information:© 2018 Royal Society of Chemistry
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
Funders:Engineering and Physical Sciences Research Council, UK (EP/K006851/1), University of Liverpool
ID Code:22923
Deposited On:16 Jan 2019 09:50 by James Walsh . Last Modified 20 Feb 2019 04:30
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