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Growth of ZnO:Al by atomic layer deposition: deconvoluting the contribution of hydrogen interstitials and crystallographic texture on the conductivity

Mauit, Ozhet, Caffrey, David orcid logoORCID: 0000-0001-7870-4428, Ainabayev, Ardak, Kaisha, Aitkazy orcid logoORCID: 0000-0001-7203-9842, Toktarbaiuly, Olzat, Sugurbekov, Yerzhigit, Sugurbekova, Gulnar orcid logoORCID: 0000-0002-6894-7247, Shvets, Igor V. orcid logoORCID: 0000-0001-7451-5435 and Fleischer, Karsten orcid logoORCID: 0000-0002-7638-4480 (2019) Growth of ZnO:Al by atomic layer deposition: deconvoluting the contribution of hydrogen interstitials and crystallographic texture on the conductivity. Thin Solid Films, 690 . ISSN 0040-6090

Abstract
© 2019 Elsevier B.V. Aluminium doped ZnO (AZO) is an interesting low cost transparent conducting oxide with further use as an inorganic transport layer in multilayer solar cells. Here we present our work on atomic layer deposited (ALD) thin films where, with optimised growth conditions, we can obtain resistivities of 1 × 10−3 Ωcm even in 50–80 nm thin films grown at low temperatures (250 °C). We discuss the influence of crystallographic texture for ALD grown films by comparing plain glass, c-plane Al2O3, and a-plane Al2O3 substrates. We show that the doping mechanism in ALD grown AZO is more complex than for e.g. sputtered material as a substantial hydrogen interstitial related background doping occurs. We compare results from as grown samples with those briefly annealed at 320 °C in nitrogen. This process leads to an increased Hall mobility due to improved grain boundary passivation, but reduced carrier concentration due to partial loss of hydrogen interstitials.
Metadata
Item Type:Article (Published)
Refereed:Yes
Uncontrolled Keywords:Aluminium doped zinc oxide; Atomic layer deposition; Crystallographic texture; Hydrogen; Transparent conducting oxide
Subjects:Physical Sciences > Chemistry
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Physical Sciences
Publisher:Elsevier
Official URL:http://dx.doi.org/10.1016/j.tsf.2019.137533
Copyright Information:© 2019 Elsevier
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
Funders:Science Foundation Ireland under grant no. 12/IA/1264, and SFI/12/RC/2278, Ministry of Education and Science of the Republic of Kazakhstan under Grant No. AP05134861 and 0115PK03029., Kazakhstan government under the Bolashak program, Nazarbayev University under the Talap program
ID Code:23916
Deposited On:29 Nov 2019 12:05 by Vidatum Academic . Last Modified 29 Oct 2021 11:23
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