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Intermolecular C-H...N and C-H...O interactions in (2S,4S,5R)-(-)-3,4-dimethyl-5-phenyl-2-(1,3-thiazol-2-yl)-1,3-oxazolidine

Fitzsimons, Lavelle M. and Gallagher, John F. orcid logoORCID: 0000-0003-4130-4556 (1999) Intermolecular C-H...N and C-H...O interactions in (2S,4S,5R)-(-)-3,4-dimethyl-5-phenyl-2-(1,3-thiazol-2-yl)-1,3-oxazolidine. Acta Crystallographica Section C, 55 (3). pp. 472-474. ISSN 0108-2701

Abstract
The title compound, C₁₄H₁₆N₂OS, prepared from (1R,2S)-(-)-ephedrine, contains the oxazolidine ring in an envelope conformation, with the nitrogen atom 0.623 (2) Å from the plane of the other four oxazolidine ring atoms. Intermolecular C--H...N and C--H...O interactions generate a two-dimensional hydrogen-bonded network, with shortest C...N and C...O distances of 3.403 (3) and 3.463 (2) Å, respectively.
Metadata
Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270198014103
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:294
Deposited On:11 Mar 2008 by DORAS Administrator . Last Modified 10 Oct 2018 12:35
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