Gallagher, John F. 
ORCID: 0000-0003-4130-4556 and Fitzsimons, Lavelle M.
(1999)
Intermolecular N-H...O and C-H...O interactions form a two-dimensional network in (2S,4S,5R)-(-)-3,4-dimethyl-5-phenyl-2-(pyrrol-2-yl)-1,3-oxazolidine.
Acta Crystallographica Section C, 55
(6).
pp. 1000-1003.
ISSN 0108-2701
Abstract
The title compound, C₁₅H₁₈N₂0, prepared from (1R,2S)-
(-)-ephedrine, crystallizes in space group P1 with two
molecules in the asymmetric unit. The oxazolidine rings
of the two molecules adopt an envelope conformation,
with the N atom 0.609 (6) and 0.623 (6)Å from the
plane of the other four oxazolidine ring atoms. Intermolecular Npyrrole--H...O and Cphenyl--H...O interactions generate a two-dimensional hydrogen-bonded network with N...O and C...O distances of 3.004 (4) and
3.051 (4)Å, respectively, and 3.599 (5) and 3.632 (5)Å,
respectively, for the two independent hydrogen-bonding
systems.
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Subjects: | Physical Sciences > Chemistry Physical Sciences > Crystallography |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
| Publisher: | International Union of Crystallography |
| Official URL: | http://dx.doi.org/10.1107/S0108270199002292 |
| Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
| ID Code: | 295 |
| Deposited On: | 11 Mar 2008 by DORAS Administrator . Last Modified 10 Oct 2018 12:34 |
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