Gallagher, John F. ORCID: 0000-0003-4130-4556 and Moriarty, Elena (1999) Intermolecular (pyrrole)N-H...π(pyrrole) interactions in bis(2-pyrrolyl)methylferrocene, an organometallic porphyrin precursor. Acta Crystallographica Section C, 55 (7). pp. 1079-1082. ISSN 0108-2701
Abstract
The title compound, C₁₉H₁₈FeN₂ or [Fe(C₅H₅)(C₁₄H₁₃-
N₂)], crystallizes in space group P2₁ln with two molecules
in the asymmetric unit. The pyrrole groups take
part in intermolecular (pyrrole)N--H...π(pyrrole) interactions
through a hydrogen-bonded ring system involving
four pyrrole groups, with N..-(pyrrole centroid)
distances in the range 3.209(3)-3.427 (3)Å and N--
H...(pyrrole centroid) angles in the range 127-139°.
Metadata
Item Type: | Article (Published) |
---|---|
Refereed: | Yes |
Subjects: | Physical Sciences > Chemistry Physical Sciences > Crystallography |
DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
Publisher: | International Union of Crystallography |
Official URL: | http://dx.doi.org/10.1107/S0108270199003625 |
Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
ID Code: | 296 |
Deposited On: | 11 Mar 2008 by DORAS Administrator . Last Modified 10 Oct 2018 12:34 |
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