Login (DCU Staff Only)
Login (DCU Staff Only)

DORAS | DCU Research Repository

Explore open access research and scholarly works from DCU

Advanced Search

Intermolecular (pyrrole)N-H...π(pyrrole) interactions in bis(2-pyrrolyl)methylferrocene, an organometallic porphyrin precursor

Gallagher, John F. orcid logoORCID: 0000-0003-4130-4556 and Moriarty, Elena (1999) Intermolecular (pyrrole)N-H...π(pyrrole) interactions in bis(2-pyrrolyl)methylferrocene, an organometallic porphyrin precursor. Acta Crystallographica Section C, 55 (7). pp. 1079-1082. ISSN 0108-2701

Abstract
The title compound, C₁₉H₁₈FeN₂ or [Fe(C₅H₅)(C₁₄H₁₃- N₂)], crystallizes in space group P2₁ln with two molecules in the asymmetric unit. The pyrrole groups take part in intermolecular (pyrrole)N--H...π(pyrrole) interactions through a hydrogen-bonded ring system involving four pyrrole groups, with N..-(pyrrole centroid) distances in the range 3.209(3)-3.427 (3)Å and N-- H...(pyrrole centroid) angles in the range 127-139°.
Metadata
Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270199003625
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:296
Deposited On:11 Mar 2008 by DORAS Administrator . Last Modified 10 Oct 2018 12:34
Documents

Full text available as:

[thumbnail of acta_crys_c_55_7.pdf]
Preview
PDF - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
465kB
Metrics

Altmetric Badge

Dimensions Badge

Downloads

Downloads

Downloads per month over past year

Archive Staff Only: edit this record