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L-shell Photoionisation Cross Sections in the S +, S 2+, S 3+ Isonuclear Sequence

Mosnier, Jean-Paul orcid logoORCID: 0000-0002-9312-1754, Kennedy, Eugene T. orcid logoORCID: 0000-0002-0710-5281, Cubaynes, Denis orcid logoORCID: 0009-0005-7019-3156, Bizau, Jean-Marc orcid logoORCID: 0000-0003-0960-9165, Guilbaud, Ségolène orcid logoORCID: 0009-0009-6161-1810, Blancard, Christophe orcid logoORCID: 0000-0003-4710-175X, McLaughlin, Brendan orcid logoORCID: 0000-0002-5917-0763, Hasoglu, Muhammet orcid logoORCID: 0000-0001-6735-9438 and Gorczyca, Thomas orcid logoORCID: 0000-0003-4117-5790 (2025) L-shell Photoionisation Cross Sections in the S +, S 2+, S 3+ Isonuclear Sequence. Journal of Physics B: Atomic, Molecular and Optical Physics . ISSN 0953-4075 (In Press)

We present absolute L-shell photoionisation cross sections for the S+, S2+, S3+ ions. The cross sections were obtained using the monochromatised photon beam delivered by the SOLEIL syn- chrotron source coupled with an ion beam extracted from an electron cyclotron resonance source (ECRIS) in the merged dual-beam configuration. The cross sections for single, double and triple ionisation were measured and combined to generate total photoionisation cross sections. For each of the S+, S2+ and S3+ ions, the photon energy regions corresponding to the excitation and ionisation of a 2p or a 2s electron (∼175-230 eV) were investigated. The experimental results are interpreted with the help of multiconfigurational Dirac-Fock (MCDF) and Breit-Pauli R-Matrix (BPRM) or Dirac R-Matrix (DARC) theoretical calculations. The former generates photoabsorption cross sec- tions from eigenenergies and eigenfunctions obtained by solving variationally the multiconfiguration Dirac Hamiltonian while the latter calculate cross sections for photon scattering by atoms. The cross sectional spectra feature rich resonance structures with narrow natural widths (typically ≤100 meV) due to 2p →nd excitations below and up to the 2p thresholds. This behaviour is consistent with the large number of inner-shell states based on correlation and spin-orbit mixed configurations having three open subshells. Strong and wide (typically∼1 eV) Rydberg series of resonances due to 2s →np excitations dominate above the 2p threshold.
Item Type:Article (In Press)
Refereed:Yes
Uncontrolled Keywords:Photionization, atomic ions
Subjects:Physical Sciences > Astronomy
Physical Sciences > Astronomy > Astrophysics
Physical Sciences > Physics
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Physical Sciences
DCU Faculties and Schools
Research Institutes and Centres
Research Institutes and Centres > National Centre for Plasma Science and Technology (NCPST)
Publisher:Institute of Physics Publishing Ltd.
Official URL:https://iopscience.iop.org/article/10.1088/1361-64...
Copyright Information:Authors
Funders:NASA, Gauss Centre for Supercomputing e.V. (https://www.gauss-centre.eu/)
ID Code:30755
Deposited On:24 Feb 2025 10:12 by Jean-Paul Mosnier . Last Modified 24 Feb 2025 10:12

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