Lees, Anthea C., Evrard, Bénédicte, Keyes, Tia E., Vos, Johannes G., Kleverlaan, Cornelis J., Alebbi, Monica and Bignozzi, Carlo A. (1999) Synthesis, spectroscopy and photophysical properties of ruthenium triazole complexes and their application as dye-molecules in regenerative solar cells. European Journal of Inorganic Chemistry, 1999 (12). pp. 2309-2317. ISSN 1434-1948
Abstract
The complexes [Ru(dcb)2(L)] (L = 3-(2-phenol)-5-(pyridin-2-yl)-1,2,4-triazole (2-ppt),
3-(4-phenol)-5-(pyridin-2-yl)-1,2,4-triazole (4-ppt), 3,5-bis(pyrazin-2-yl)-1,2,4-triazole (bpzt),
3-(2-phenol)-5-(pyrazin-2-yl)-1,2,4-triazole (2-ppzt) and dcb = 4,4’-(CO2H)2-2,2’-bipyridine)
have been synthesized, spectroscopically characterized and anchored to nanocrystalline TiO2
electrodes for the conversion of light into electricity in regenerative solar cells. The different
efficiencies observed have been rationalized on the basis of an analytical expression relating
the incident photon-to-current-conversion efficiency (IPCE) to the kinetic parameters of the
relevant electron transfer processes involved in the solar cell.
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Uncontrolled Keywords: | ruthenium triazole titanium electron transfer sensitizers |
| Subjects: | Physical Sciences > Chemistry |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences Research Institutes and Centres > National Centre for Sensor Research (NCSR) |
| Publisher: | John Wiley & Sons |
| Official URL: | http://dx.doi.org/ 10.1002/(SICI)1099-0682(199912)... |
| ID Code: | 36 |
| Deposited On: | 27 Oct 2006 by DORAS Administrator . Last Modified 27 Sep 2019 11:25 |
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