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The structure of triphenylgermanium hydroxide

Ferguson, George, Gallagher, John F. orcid logoORCID: 0000-0002-7112-7450, Murphy, Denis, Spalding, Trevor R., Glidewell, Christopher and Holden, H. Diane (1992) The structure of triphenylgermanium hydroxide. Acta Crystallographica Section C, 48 (7). pp. 1228-1231. ISSN 0108-2701

Abstract
C18H~6GeO, Mr = 320.9, triclinic, Pi, a = 15.408 (6), b = 19.974 (7), c = 23.264 (11) A, a = 107.78 (4), 13 = 1.03.54 (4), y= 101.51 (3) °, V = 6338 (5)/~3, Z = 16, Dx = 1.34 g cm -3, a(Mo Ka) = 0.71073A, /z = 19.1cm-1, F(000)=2624, T= 293 K, R = 0.055 for 6846 observed reflections. The eight independent molecules in the asymmetric unit form two independent O--H...O hydrogen-bonded tetramers with the O atoms in a flattened tetrahedral arrangement [hydrogen-bond distances in the range 2.609 (11) to 2.657 (11)A]. The Ge atoms are tetrahedrally coordinated with mean Gc O 1.791 (7) and Gc C 1.931 (8) A.
Metadata
Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270191015056
Copyright Information:© 1992 International Union of Crystallography
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:3611
Deposited On:18 Mar 2009 17:18 by DORAS Administrator . Last Modified 10 Oct 2018 12:52
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