The interaction of two counter-propagating laser-produced plasmas was studied using simultaneous imaging and spectroscopic techniques. Spectrally-filtered time-gated ICCD imaging was used to obtain information about the spatial dynamics and temporal evolution of the collision process. While, time-resolved imaging spectroscopy was used to determine the spatial and temporal distributions of electron temperature and density within the interaction region. We examine specifically the interaction of plasmas whose parameters match those typically used in pulsed laser deposition of thin films. These low temperature plasmas are highly collisional leading to the creation of a pronounced stagnation layer in the interaction region.