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Regioselective functionalization of tetrabromophenanthroline-ruthenium complexes

Rau, Sven, Fischer, Reinald, Jäger, Michael, Schäfer, Bernhard, Meyer, Susann, Kreisel, Günter, Görls, Helmar, Rudolf, Manfred, Henry, William and Vos, Johannes G. (2004) Regioselective functionalization of tetrabromophenanthroline-ruthenium complexes. European Journal of Inorganic Chemistry, 2004 (10). pp. 2001-2003. ISSN 1434-1948

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Abstract
Structural, photophysical and -chemical characterisation and reactivity of a novel polypyridyl ruthenium complex based on 3,5,6,8-tetra-bromophenanthroline are discussed. Signal storage at a molecular level is great challenge for chemistry.1 The possibility of connecting different functionalities selectively to one ligand of a metal complex may open the route towards higher integrated molecular units capable of processing various external stimuli in a predesignated order. The implementation of this concept demands ligands with a multitude of potential connecting groups which can selectively be transformed.2 3-bromo- and 3,8-dibromophenanthrolines have proved useful for the preparation of mononuclear3 and multiheteronuclear complexes.4 These systems have found applications ranging from DNA photoprobes5 to metalloligands in catalysis.6 A very useful feature of this bromophenanthroline ruthenium complexes is their susceptibility towards nucleophilic aromatic substitution which is very well established.
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Item Type:Article (Published)
Refereed:Yes
Uncontrolled Keywords:ruthenium; nucleophilic substitution; phenanthroline;
Subjects:Physical Sciences > Chemistry
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Research Initiatives and Centres > National Centre for Sensor Research (NCSR)
Publisher:John Wiley & Sons
Official URL:http://dx.doi.org/10.1002/ejic.200400163
ID Code:35
Deposited On:27 Oct 2006 by DORAS Administrator . Last Modified 27 Sep 2019 11:26
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