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pH and photo-responsive hydrogels based on acrylic acid and acrylamide

Dunne, Aishling, Mac Ardle, Siobhán, Florea, Larisa orcid logoORCID: 0000-0002-4704-2393 and Diamond, Dermot orcid logoORCID: 0000-0003-2944-4839 (2015) pH and photo-responsive hydrogels based on acrylic acid and acrylamide. In: 12th International conference on Materials Chemistry (MC12), 20-23 July 2015, University of York, UK.

Hydrogels are three-dimensional polymeric networks that can absorb and retain large quantities of water in relation to their physical size. By incorporating stimuli-responsive units into the gel structure, hydrogel materials can be actuated by external stimuli such as photo, thermal, electro and pH, respectively. In this study, pH responsive hydrogels were developed by using copolymers of acrylic acid (AA) and acrylamide (Am) in different molar ratios (30:70, 50:50 and 70:30, respectively). At pH above the pKa of AA (pH>4.5) the AA dissociates to the more hydrophilic acrylate (A-) form triggering swelling of the hydrogel. In contrast, at pH < 4.5, the hydrogel contracts due to the formation of the hydrophilic AA form in the polymer backbone, which triggers release of water from the gel. In order to turn this pH response into a photo-response, a reversible photo-acid generator, spiropyran acrylate (SP-A), was copolymerised in the polymer backbone. In acidic environments, the SP-A will spontaneously convert to the protonated hydrophilic merocyanine (MC-H+) form and switch back to the hydrophobic SP-A when exposed to white light, expelling a proton in the process. The switching between these two forms can be used to trigger LCST behaviour in the gel, leading to photo-controlled swelling/contraction due to water uptake and release. The composition used for the photo responsive hydrogel was AA: Am: SP-A in a 10:10:1 molar ratio. When the hydrogel is immersed in water, in the dark, the AA dissociates and the proton is taken by the SP-A to form MC-H+, which gives the hydrogel a yellow colour. Under these conditions (A-, MC-H+) the polymer chains are more hydrophilic causing the hydrogel to expand (Fig. 1, initial point). However, when exposed to white light, the MC-H+ is converted back to the SP-A form (colourless) expelling a proton, decreasing the local pH, and protonating the AA. This makes the polymer chain less hydrophilic and the hydrogel contracts (Fig. 1, 0-10 min). As seen in Fig. 1, this process is reversible and with the initial photo-contraction complete in seconds. After ca. 10 min, the white light is switched off, and the hydrogel reswells to about 95% of its fully hydrated size after ca. 15 min in the dark.
Item Type:Conference or Workshop Item (Poster)
Event Type:Conference
Uncontrolled Keywords:Hydrogels; pH-responsive materials; Photo-responsive materials; Spiropyran-acrylate; Acrylic acid
Subjects:Physical Sciences > Chemical detectors
Physical Sciences > Organic chemistry
Physical Sciences > Chemistry
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Research Institutes and Centres > INSIGHT Centre for Data Analytics
Research Institutes and Centres > National Centre for Sensor Research (NCSR)
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
Funders:Science Foundation Ireland, Insight, centre for Data analytics
ID Code:20723
Deposited On:04 Aug 2015 11:03 by Aishling Dunne . Last Modified 14 Sep 2018 15:06

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