cis-Tetracarbonylbis[tris(p-fluorophenyl)phosphine]molybdenum(0)
Alyea, Elmer C., Ferguson, George, Gallagher, John F. 
ORCID: 0000-0002-7112-7450 and Song, Shuquan
(1994)
cis-Tetracarbonylbis[tris(p-fluorophenyl)phosphine]molybdenum(0).
Acta Crystallographica Section C, 50
(7).
pp. 1084-1087.
ISSN 0108-2701
Abstract
The molecule c/s-tetracarbonylbis[tris(p-fluorophenyl)-
phosphine] molybdenum(0), [Mo(C18HI2F3P)2(CO)4],
has twofold crystallographic symmetry; the Mo geometry
is irregular octahedral, with principal dimensions Mo-
P 2.5644 (4), Mo--C (troans to P) 1.9869 (16), Mo--C
(trans to C) 2.0310 (18) A, P--Mo--P 107.33 (1), trans-
P--Mo--C 166.76 (5)and trans-C--Mo--C 174.31 (8)°.
The P geometry is irregular tetrahedral, with enlarged
Mo--P--C [average 115.94 (5)°] and reduced C--P--C
[average 102.22 (7)°] angles. 95Mo NMR chemical shift
data are in accord with the observed structure.
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Subjects: | Physical Sciences > Organic chemistry Physical Sciences > Crystallography |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
| Publisher: | International Union of Crystallography |
| Official URL: | http://dx.doi.org/10.1107/S0108270193014052 |
| Copyright Information: | © 1994 International Union of Crystallography |
| Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
| ID Code: | 2473 |
| Deposited On: | 11 Mar 2009 17:54 by DORAS Administrator . Last Modified 10 Oct 2018 12:48 |
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