Skip to main content
DORAS
DCU Online Research Access Service
Login (DCU Staff Only)
cis-Tetracarbonylbis[tris(p-fluorophenyl)phosphine]molybdenum(0)

Alyea, Elmer C., Ferguson, George, Gallagher, John F. ORCID: 0000-0002-7112-7450 and Song, Shuquan (1994) cis-Tetracarbonylbis[tris(p-fluorophenyl)phosphine]molybdenum(0). Acta Crystallographica Section C, 50 (7). pp. 1084-1087. ISSN 0108-2701

Full text available as:

[img]
Preview
PDF - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
477kB

Abstract

The molecule c/s-tetracarbonylbis[tris(p-fluorophenyl)- phosphine] molybdenum(0), [Mo(C18HI2F3P)2(CO)4], has twofold crystallographic symmetry; the Mo geometry is irregular octahedral, with principal dimensions Mo- P 2.5644 (4), Mo--C (troans to P) 1.9869 (16), Mo--C (trans to C) 2.0310 (18) A, P--Mo--P 107.33 (1), trans- P--Mo--C 166.76 (5)and trans-C--Mo--C 174.31 (8)°. The P geometry is irregular tetrahedral, with enlarged Mo--P--C [average 115.94 (5)°] and reduced C--P--C [average 102.22 (7)°] angles. 95Mo NMR chemical shift data are in accord with the observed structure.

Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270193014052
Copyright Information:© 1994 International Union of Crystallography
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:2473
Deposited On:11 Mar 2009 17:54 by DORAS Administrator . Last Modified 10 Oct 2018 12:48

Downloads

Downloads per month over past year

Archive Staff Only: edit this record

Altmetric
- Altmetric
+ Altmetric
  • Student Email
  • Staff Email
  • Student Apps
  • Staff Apps
  • Loop
  • Disclaimer
  • Privacy
  • Contact Us