Fanni, Stefano, Di Pietro, Cinzia, Serroni, Scolastica, Campagna, Sebastiano and Vos, Johannes G. (2000) Ni(0) catalysed homo-coupling reactions: a novel route towards the synthesis of multinuclear ruthenium polypyridine complexes featuring made-to-order properties. Inorganic Chemistry Communications, 3 (1). pp. 42-44. ISSN 1387-7003
Abstract
A new synthetic procedure for the efficient preparation of dinuclear ruthenium(II) polypyridyl complexes is reported. The compounds
synthesised are [(bpy)2Ru(BPBT)Ru(bpy)2](PF6)2 and [(bpy)2Ru(BPZBT)Ru(bpy)2](PF6)2 (bpys2,29-bipyridine; H2BPBTs5,59-
bis(pyridin-2-yl)-3,39-bis(1,2,4-triazole); H2BPZBTs5,59-bis(pyrazin-2-yl)-3,39-bis(1,2,4-triazole). Electrochemical experiments show
that the two dinuclear systems investigated exhibit pH switchable intercomponent interactions.
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Uncontrolled Keywords: | ruthenium complexes; coupling reactions; electrochemistry; dinuclear complexes; |
| Subjects: | Physical Sciences > Chemistry |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
| Publisher: | Elsevier |
| Official URL: | http://dx.doi.org/10.1016/S1387-7003(99)00182-3 |
| Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
| ID Code: | 32 |
| Deposited On: | 27 Oct 2006 by DORAS Administrator . Last Modified 19 Jul 2018 14:40 |
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