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The Approach to Equilibrium in Statistical Thermodynamics – Do We Really Need Coarse-graining?

McGlynn, Enda orcid logoORCID: 0000-0002-3412-9035 (2026) The Approach to Equilibrium in Statistical Thermodynamics – Do We Really Need Coarse-graining? European Journal of Physics, 47 . 055101-1-055101-10. ISSN 1361-6404

Abstract
The technique of coarse-graining is conventionally used in both introductory and more advanced textbooks on statistical mechanics and thermodynamics when discussing a thermodynamic state described by an ensemble approaching equilibrium. In quantum statistical thermodynamics there exists a natural uncertainty-limited phase space volume element, but in the case of classical statistical thermodynamics no such natural phase space volume element exists and coarse-graining by its nature can appear as a rather arbitrary and ad-hoc procedure for students first encountering it. The present work discusses the approach to equilibrium in the ensemble picture, based on observable thermodynamic properties of the system in question. We suggest that a fruitful teaching approach can be based on the perspective that the system has reached thermodynamic equilibrium (distinct from statistical equilibrium) if all its observable macroscopic thermodynamic properties are indistinguishable from those of a canonical ensemble with the same observable macroscopic properties. This differs to an approach based on whether the probability distribution function (specifically the integral of the natural logarithm of the probability distribution) match those of a canonical distribution (which they cannot do in thermally isolated systems, due to the Liouville theorem). These ideas are essentially those of “weak convergence”, normally encountered in more mathematically advanced treatments, but whose basic ideas can be motivated with a simple mathematical outline, and is based on a set of common and reasonable assumptions concerning the evolution of probability distribution functions in a thermally isolated system. The approach may help alleviate student concerns over the use of coarse-graining in classical statistical thermodynamics. A relatively slight elevation in the mathematical level of the concepts therefore provides a considerable gain in clarity and coherence of the emergent physical picture, and aligns with previous work by Jaynes, recently highlighted by me, on the definition of entropy in the ensemble picture.
Metadata
Item Type:Article (Published)
Refereed:Yes
Uncontrolled Keywords:Statistical, mechanics, thermodynamics, entropy, Liouville, coarse-graining
Subjects:Physical Sciences > Physics
Physical Sciences > Statistical physics
Physical Sciences > Physics education
Mathematics > Probabilities
Mathematics > Stochastic analysis
Mathematics > Statistics
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health
DCU Faculties and Schools > Faculty of Science and Health > School of Physical Sciences
Publisher:Institute of Physics Publishing Ltd.
Official URL:https://iopscience.iop.org/article/10.1088/1361-64...
Copyright Information:Authors
ID Code:33529
Deposited On:05 Oct 2026 10:21 by Enda Mcglynn . Last Modified 05 Oct 2026 10:21
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